(S)-(-)-4-Benzyl-2-oxazolidinone, 99%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11433767	Thermo Scientific Alfa Aesar A18236.03	1 g
11443767	Thermo Scientific Alfa Aesar A18236.06	5 g
11453767	Thermo Scientific Alfa Aesar A18236.14	25 g

Description

(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.

Solubility
Insoluble in water.

Notes
Hygroscopic. Incompatible with oxidizing agents.

Chemical Identifiers

• CAS: 90719-32-7
• Molecular Weight (g/mol): 177.20
• InChI Key: OJOFMLDBXPDXLQ-VIFPVBQESA-N
• PubChem CID: 736225
• SMILES: O=C1N[C@@H](CC2=CC=CC=C2)CO1

• Molecular Formula: C10H11NO2
• MDL Number: MFCD00064496
• Synonym: s-4-benzyl-2-oxazolidinone, s-4-benzyloxazolidin-2-one, 4s-4-benzyl-1,3-oxazolidin-2-one, s---4-benzyl-2-oxazolidinone, s-4-benzyl-oxazolidin-2-one, 2-oxazolidinone, 4-phenylmethyl-, 4s, s-+-4-benzyl-2-oxazolidinone, s-4-phenylmethyl-2-oxazolidinone, 4s-4-phenylmethyl-1,3-oxazolidin-2-one
• IUPAC Name: (4S)-4-benzyl-1,3-oxazolidin-2-one

Specifications

• Melting Point: 87°C to 89°C
• Molecular Formula: C10H11NO2
• Beilstein: 3649667
• Solubility Information: Insoluble in water.
• SMILES: O=C1N[C@@H](CC2=CC=CC=C2)CO1
• Molecular Weight (g/mol): 177.20
• Formula Weight: 177.2
• Sensitivity: Hygroscopic
• Chemical Name or Material: (S)-(-)-4-Benzyl-2-oxazolidinone

• CAS: 90719-32-7
• MDL Number: MFCD00064496
• Synonym: s-4-benzyl-2-oxazolidinone, s-4-benzyloxazolidin-2-one, 4s-4-benzyl-1,3-oxazolidin-2-one, s---4-benzyl-2-oxazolidinone, s-4-benzyl-oxazolidin-2-one, 2-oxazolidinone, 4-phenylmethyl-, 4s, s-+-4-benzyl-2-oxazolidinone, s-4-phenylmethyl-2-oxazolidinone, 4s-4-phenylmethyl-1,3-oxazolidin-2-one
• InChI Key: OJOFMLDBXPDXLQ-VIFPVBQESA-N
• IUPAC Name: (4S)-4-benzyl-1,3-oxazolidin-2-one
• PubChem CID: 736225
• Optical Rotation: −64° (c=1 in Chloroform)
• Percent Purity: 99%

Safety and Handling

P261-P262-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P314-P330-P332+P313-P362-P501c

H302-H315-H320-H335-H373

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

RUO – Research Use Only