sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10325942	Thermo Scientific Acros 187541000	100 mL	AcroSeal™ Glass bottle
10568513	Thermo Scientific Acros 187548000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 598-30-1, 110-82-7, 110-54-3
• Molecular Weight (g/mol): 64.06
• InChI Key: VATDYQWILMGLEW-UHFFFAOYNA-N
• PubChem CID: 102446
• SMILES: [Li]C(C)CC

• Molecular Formula: C4H9Li
• MDL Number: MFCD00009323
• Synonym: sec-butyllithium, s-buli, s-butyllithium, s-butyl lithium, unii-5yv3gii1tb, lithium, 1-methylpropyl, 5yv3gii1tb, secbutyllithium, b-butyllithium, sec-butyllitium
• IUPAC Name: (butan-2-yl)lithium

Specifications

• Color: Colorless
• Molecular Formula: C4H9Li
• MDL Number: MFCD00009323
• Density: 0.7500g/mL
• Solubility Information: Solubility in water: reacts (forming lioh and butane).
• SMILES: [Li]C(C)CC
• Molecular Weight (g/mol): 64.06
• Formula Weight: 64.06
• Specific Gravity: 0.75
• Physical Form: Liquid

• CAS: 598-30-1, 110-82-7, 110-54-3
• Linear Formula: C₂H₅CH(CH₃)Li
• Fieser: 09,87; 10,75; 12,97; 16,56
• Synonym: sec-butyllithium, s-buli, s-butyllithium, s-butyl lithium, unii-5yv3gii1tb, lithium, 1-methylpropyl, 5yv3gii1tb, secbutyllithium, b-butyllithium, sec-butyllitium
• InChI Key: VATDYQWILMGLEW-UHFFFAOYNA-N
• IUPAC Name: (butan-2-yl)lithium
• PubChem CID: 102446
• Percent Purity: 10.5 to 12.5% (as BuLi) (Active base)
• Flash Point: −17°C
• Chemical Name or Material: sec-Butyllithium, 1.3M Solution in Cyclohexane/hexane (92/8)

Safety and Handling

GHS P Statement May cause drowsiness or dizziness. Very toxic to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure if inhaled. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Catches fire spontaneously if exposed to air. Reacts violently with water.

GHS P Statement Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air.

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 209-927-7

missing translation for 'tsca' : TSCA

Product Identifier

• sec-Butyllithium, 1.3M solution in cyclohexane/hexane (92/8)

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Pyrophoric solid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Reproductive toxicity Category 2
• ACUTE AQUATIC Acute 1
• LONG-TERM AQUATIC HAZARD Chronic 1
• Specific target organ toxicity Category 3
• Specific target organ toxicity after repeated exposure Category 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H336-May cause drowsiness or dizziness.
• H410-Very toxic to aquatic life with long lasting effects.
• H314-Causes severe skin burns and eye damage.
• H304-May be fatal if swallowed and enters airways.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• EUH014-Reacts violently with water.

Precautionary Statement

• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P222-Do not allow contact with air.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.

Supplemental information

• MIXTURE LIST-Contains : Hexane, Lithium, (1-methylpropyl), Cyclohexane

RUO – Research Use Only