9-Phenanthrylmagnesium bromide, 0.5M solution in THF, AcroSeal™, Thermo Scientific™

Description

 

This Thermo Scientific brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Specifications

• CAS: 71112-64-6, 109-99-9
• CAS Min %: 11.91, 82.13
• CAS Max %: 17.87, 88.09
• Color: Yellow to Brown
• Density: 0.9450g/mL
• Flash Point: −17°C
• Packaging: AcroSeal™ Glass Bottle
• Molecular Formula: C14H9BrMg
• MDL Number: MFCD00672008
• Quantity: 50 mL
• Specific Gravity: 0.945
• Synonym: 9-phenanthrylmagnesium bromide, 9-phenanthryl-magnesiumbromid, magnesium,bromo-9-phenanthrenyl, magnesium,9h-phenanthren-9-ide,bromide, bromo phenanthren-9-yl magnesium, 9-phenanthrylmagnesium bromide, 0.5 m in thf, 9-phenanthrylmagnesium bromide, 0.25 m in 2-methf, 9-phenanthrylmagnesium bromide 0.5 m in tetrahydrofuran, grignard reagent
• Solubility Information: Solubility in water: reacts.
• InChI Key: ACMUZKQPXSHTGB-UHFFFAOYSA-M
• SMILES: Br[Mg]C1=CC2=C(C=CC=C2)C2=C1C=CC=C2
• IUPAC Name: magnesium;9H-phenanthren-9-ide;bromide
• Molecular Weight (g/mol): 281.44
• PubChem CID: 12396678
• Formula Weight: 281.43
• Physical Form: Solution
• Chemical Name or Material: 9-Phenanthrylmagnesium bromide

Safety and Handling

Product Identifier

• 9-Phenanthrylmagnesium bromide, 0.5M solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only