n-Hexyllithium, 2.5M (33 wt.%) solution in hexane, AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 21369-64-2, 110-54-3
• Molecular Formula: C₆H₁₃Li
• Molecular Weight (g/mol): 92.11
• MDL Number: MFCD00191446
• InChI Key: CETVQRFGPOGIQJ-UHFFFAOYSA-N
• Synonym: n-hexyllithium, lithium, hexyl, hexyllithium, hexyl lithium, hexyl-lithium, lithium hexane, n-hexyllithiurn, n-hexyllitium, n-hexyl lithium, hexli
• PubChem CID: 2733163
• IUPAC Name: lithium;hexane
• SMILES: [Li+].CCCCC[CH2-]

• CAS Min %: 32.8, 66.8
• CAS Max %: 33.2, 67.2
• Color: Orange to Yellow
• Density: 0.6900g/mL
• Flash Point: −26°C
• Packaging: AcroSeal™ Glass Bottle
• Linear Formula: LiCH₂CH₂CH₂CH₂CH₂CH₃
• Quantity: 800 mL
• Specific Gravity: 0.69
• Solubility Information: Solubility in water: vigorous reaction.
• Formula Weight: 92.11
• Percent Purity: 32.8 to 33.2% (as HexLi)
• Physical Form: Solution
• Chemical Name or Material: n-Hexyllithium, 33 wt. % in n-hexane

Safety and Handling

Product Identifier

• n-Hexyllithium, 33 wt.% solution in n-hexane

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 2
• Substance which\, in contact with water\, emits flammable gases Category 1
• Pyrophoric liquid Category 1
• Aspiration toxicity Category 1
• Skin corrosion/irritation Category 1 A
• Serious eye damage/eye irritation Category 1
• Reproductive toxicity Category 2
• Specific target organ toxicity Category 3
• Specific target organ toxicity after repeated exposure Category 2
• LONG-TERM AQUATIC HAZARD Chronic 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P231+P232-Handle under inert gas. Protect from moisture.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Hydrocarbons, C6, n-alkanes, isoalkanes,cyclics, 5-50% n-hexane, n-Hexyllithium

RUO – Research Use Only